HyLoSal

Hydrate Salt Removal Technology

mOTIVATION

Demand for freshwater has increased globally and substantially due to the increased population as well as the large expansion in industrial activities. The depletion of fresh groundwater inspires humans to find an alternative water supply. Ocean water has a huge potential of becoming an alternative water resource provided appropriate and adequate desalination technology. Desalination is a separation process that reduces the total dissolved solids (TDS), i.e. salts content of saline water to an acceptable level. The most common desalination methods are thermal distillation processes such as Multi-Effect Distillation(MED), Multi-Stage Flash (MSF), and filtration processes such as Reverse Osmosis (RO), Electro-Dialysis (ED), Membrane Distillation (MD). In thermal distillation, saline water is heated until water vapor separates from the salt and the other components. A filtration method involves applying a high pressure to push saline water through a filter and separate water from salt. The biggest concern that prevents desalination processes from becoming mainstream is their high capital expenditures due to the extremely high energy consumption.


A desalination process involves three liquid streams: feedwater, processed, and brine. The energy requirements, which determine project economics, vary depending on the feedwater type. For an RO process, the initial pressurization of the feedwater makes up the majority of the energy consumption. Various benchmarking studies and economic analyses were conducted around the globe, and the results indicate the development of an industrial hybrid system coupling freezing/hydrate and reverse osmosis as a future aspired technology as seawater can be processed to brackish water before going to an RO process. In 2018, Babu and his team concluded that the coupling of freezing and RO reduces the total energy consumption by 4 times. As the hydrate crystals contain a smaller quality of salts compared to the feedwater.

THe approach

This project proposes the research and development of a novel technology involving closed-loop hydrate desalination from freezing using isenthalpic expansion of carbon dioxide (CO2) gas. CO2 is chosen for its high Joules-Thompson coefficient. The device is a cylindrical vessel with two main chambers that are separated by a thin layer used for vacuum insulation. CO2 gas is compressed into a liquid and stored in the outer layer. Liquid CO2 will be vented into the inner chamber through a system of Joules-Thomson valves to create an isenthalpic expansion. The inner chamber has one port at the top and one port at the bottom with a downward slope to assist with water drainage. During the expansion, the excess gas is vented to the top into a storage tank for the next cycle through a back pressure regulator (BPR) to regulate the inner chamber’s pressure such that the condition is optimal for hydrate formation. The bottom vent is kept closed to retain colder water until the hydrate is formed.

MARKET OPPORTUNITY

Total desalination capacity exceeded 64 million m3/day in 2010 and was close to 98 million m3/day in 2015. There are around 16,000 operational desalination plants produced around the world, of which 15.5% are produced in Saudi Arabia, followed by 11.9% by the U.S.A, and 7.5% by China. The largest user of the desalination plants is the municipal sector with 62.3%, followed by 30.2% from industrial application, 4.8% from the power sector, and 1.8% from the agriculture sector. RO is by far the most widely used desalination technology consisting of 84% of the total number of operational desalination plants and producing 69% of the total global produced water. The two major thermal technologies, MSF and MED produced 18% and 7%, respectively of the total produced water.

In terms of feedwater, 61% of produced water comes from seawater, followed by 21% and 8%, respectively by brackish water and river water. For membrane technologies, low TDS salinity feedwater requires lower applied pressure than high salinity feedwater type for desalination, causing lower energy consumption per unit of water produced I.e. for brackish water desalination, the operating pressures range from 250 to 400 psi, and for seawater/brine desalination from 800 to 1,000 psi.

The main factor of the initial energy cost is TDS, TDS of water from 3,000-10,000 ppm is considered brackish, and above 35,000 ppm is categorized as seawater/brine.

The combination of this closed-loop hydration technology and R.O could furthermore increase the efficiency of the whole hybrid desalination process by lowering capital and operational expenditures hence increasing the rate of return and attracting future desalination plant development.



Questions?

Contact bradley@hylosal.com to get more information on the project